Constructing π-Electron-Conjugated Diarylbutadiyne-Based Polydiacetylene under Molecular Framework Controlled by Hydrogen Bond and Side-Chain Substituent Position.
Macromol Rapid Commun
; 37(8): 685-90, 2016 Apr.
Article
em En
| MEDLINE
| ID: mdl-26924039
ABSTRACT
Diarylbutadiyne derivatives are ideal monomers for providing the π-electron-conjugated system of polydiacetylenes (PDAs). The geometrical parameters for diacetylene topochemical polymerization are known. However, control of the molecules under these parameters is yet to be addressed. This work shows that by simply tailoring diarylbutadiyne with amide side-chain substituents, the arrangement of the substituents and the resulting hydrogen bond framework allows formation of π-electron-conjugated PDA.
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Polímeros
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En
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Macromol Rapid Commun
Ano de publicação:
2016
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Article