Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity.
Org Lett
; 18(15): 3570-3, 2016 08 05.
Article
em En
| MEDLINE
| ID: mdl-27403763
ABSTRACT
Gold mesoionic carbenes having a chiral sulfoxide group attached to the C4 position of the five membered ring have been prepared and tested as catalysts in the cycloisomerization of enynes. These new catalysts are very efficient, with the sulfoxide moiety playing a key role in their activity and the N1-substituent in control of the regioselectivity of these processes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Lett
Ano de publicação:
2016
Tipo de documento:
Article