A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc3N@Ih-C80(-))2 dimers.
Chem Commun (Camb)
; 52(71): 10763-6, 2016 Sep 14.
Article
em En
| MEDLINE
| ID: mdl-27511304
ABSTRACT
Reduction of scandium nitride clusterfullerene, Sc3N@Ih-C80, by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}2(Sc3N@Ih-C80(-))2·2.5C6H4Cl2 (1) salt. The Sc3N@Ih-C80Ë(-) radical anions are dimerized to form single-bonded (Sc3N@Ih-C80(-))2 dimers.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2016
Tipo de documento:
Article