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Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides.
Li, Yuanyuan; Qiu, Dachuan; Gu, Rongrong; Wang, Junli; Shi, Jiarong; Li, Yang.
Afiliação
  • Li Y; School of Chemistry and Chemical Engineering, Chongqing University , 174 Shazheng Street, Chongqing 400030, P. R. China.
  • Qiu D; School of Chemistry and Chemical Engineering, Chongqing University , 174 Shazheng Street, Chongqing 400030, P. R. China.
  • Gu R; School of Chemistry and Chemical Engineering, Chongqing University , 174 Shazheng Street, Chongqing 400030, P. R. China.
  • Wang J; School of Chemistry and Chemical Engineering, Chongqing University , 174 Shazheng Street, Chongqing 400030, P. R. China.
  • Shi J; School of Chemistry and Chemical Engineering, Chongqing University , 174 Shazheng Street, Chongqing 400030, P. R. China.
  • Li Y; School of Chemistry and Chemical Engineering, Chongqing University , 174 Shazheng Street, Chongqing 400030, P. R. China.
J Am Chem Soc ; 138(34): 10814-7, 2016 08 31.
Article em En | MEDLINE | ID: mdl-27527334
An aryne 1,2,3-trisubstitution with aryl allyl sulfoxides is accomplished, featuring an incorporation of C-S, C-O, and C-C bonds on the consecutive positions of a benzene ring. The reaction condition is mild with broad substrate scope. Preliminary mechanistic study suggests a cascade formal [2 + 2] reaction of aryne with S═O bond, an allyl S → O migration, and a Claisen rearrangement.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2016 Tipo de documento: Article