Nanoscale Density Fluctuations in Ionic Liquid Binary Mixtures with Nonamphiphilic Compounds: First Experimental Evidence.
J Phys Chem B
; 120(40): 10540-10546, 2016.
Article
em En
| MEDLINE
| ID: mdl-27700097
ABSTRACT
A complex mesoscopic organization is observed in systems containing ethylammonium nitrate (EAN) and two nonamphiphilic compounds, using wide and small angle X-ray scattering and molecular dynamics simulations. The macroscopically homogeneous mixtures exhibit a separation where an ionic liquid-rich region is percolating a molecular liquid-rich one, but no unmixing is observed. This effect was already reported in EAN-alcohol mixtures, but the models proposed so far cannot explain this behavior for a nonamphiphilic compound.
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MEDLINE
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En
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J Phys Chem B
Ano de publicação:
2016
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Article