Proton-driven coordination-induced spin state switch (PD-CISSS) of iron(ii) complexes.
Chem Commun (Camb)
; 53(5): 971-974, 2017 Jan 16.
Article
em En
| MEDLINE
| ID: mdl-28044155
ABSTRACT
Here we report the completely reversible spin state switch of the naturally diamagnetic tris(bipyridine)iron(ii) complex and the spin crossover complex bis(2,6-bis(1H-pyrazol-3-yl)pyridine)iron(ii) by the variation of the pH followed by 1H-NMR, UV-Vis spectroscopy, and magnetic and relaxivity measurements in solution and as composite materials encapsulated in a zeolite matrix.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2017
Tipo de documento:
Article