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Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex.
Xiang, Jing; Liu, Jia-Jia; Chen, Xiao-Xiang; Jia, Li-Hui; Yu, Fei; Wang, Bing-Wu; Gao, Song; Lau, Tai-Chu.
Afiliação
  • Xiang J; College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434020, HuBei, P. R. China. xiangjing@yangtzeu.edu.cn.
  • Liu JJ; State Key Laboratory of Rare Earth Materials Chemistry and Applications and PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, China. gaosong@pku.edu.cn.
  • Chen XX; State Key Laboratory of Rare Earth Materials Chemistry and Applications and PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, China. gaosong@pku.edu.cn.
  • Jia LH; School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, P. R. China.
  • Yu F; College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434020, HuBei, P. R. China. xiangjing@yangtzeu.edu.cn.
  • Wang BW; State Key Laboratory of Rare Earth Materials Chemistry and Applications and PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, China. gaosong@pku.edu.cn.
  • Gao S; State Key Laboratory of Rare Earth Materials Chemistry and Applications and PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, China. gaosong@pku.edu.cn.
  • Lau TC; Department of Biology and Chemistry, Institute of Molecular Functional Materials, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong, China.
Chem Commun (Camb) ; 53(9): 1474-1477, 2017 Jan 26.
Article em En | MEDLINE | ID: mdl-28083575
The synthesis and structure of an 8-coordinate Fe(ii) compound [FeII(L1)2](ClO4)2 (1) with a [FeN4O4] core are reported. 1 exhibits uni-axial anisotropy for which a slow magnetic relaxation is observed under 1.4 kOe dc field. It is the first example of an 8-coordinate Fe(ii) complex exhibiting field-induced single-molecule magnet (SMM) behaviour.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2017 Tipo de documento: Article