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Nitrogen-Bridged Metallodiazaporphyrin Dimers: Synergistic Effects of Nitrogen Bridges and meso-Nitrogen Atoms on Structure and Properties.
Kawamata, Masahiro; Sugai, Takuma; Minoura, Mao; Maruyama, Yasuhisa; Furukawa, Ko; Holstrom, Cole; Nemykin, Victor N; Nakano, Haruyuki; Matano, Yoshihiro.
Afiliação
  • Kawamata M; Department of Chemistry, Faculty of Science, Niigata University, Nishi-ku, Niigata, 950-2181, Japan.
  • Sugai T; Department of Chemistry, Faculty of Science, Niigata University, Nishi-ku, Niigata, 950-2181, Japan.
  • Minoura M; Department of Chemistry, College of Science, Rikkyo University, Toshima-ku, Tokyo, 171-8501, Japan.
  • Maruyama Y; Department of Fundamental Sciences, Graduate School of Science and Technology, Niigata University, Nishi-ku, Niigata, 950-2181, Japan.
  • Furukawa K; Center for Instrumental Analysis, Institute for Research Promotion, Niigata University, Nishi-ku, Niigata, 950-2181, Japan.
  • Holstrom C; Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota, 55812-2496, USA.
  • Nemykin VN; Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota, 55812-2496, USA.
  • Nakano H; Department of Chemistry, University of Manitoba, Winnipeg MB, R3T 2N2, Canada.
  • Matano Y; Department of Chemistry, Graduate School of Science, Kyushu University, Nishi-ku, Fukuoka, 819-0395, Japan.
Chem Asian J ; 12(7): 816-821, 2017 Apr 04.
Article em En | MEDLINE | ID: mdl-28181737
ABSTRACT
NH-bridged and pyrazine-fused metallodiazaporphyrin dimers have been prepared from nickel(II) and copper(II) complexes of 3-amino-5,15-diazaporphyrin by Pd-catalyzed C-N cross-coupling and oxidative dimerization reactions, respectively. The synergistic effects of the nitrogen bridges and meso-nitrogen atoms play major roles in enhancing the light-harvesting properties and delocalization of an electron spin over the entire π-skeletons of the metallodiazaporphyrin dimers.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2017 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2017 Tipo de documento: Article