An unusual nitride network of aluminum-centered octahedra and phosphorus-centered tetrahedra and structure determination from microcrystalline samples.
Chem Commun (Camb)
; 53(18): 2709-2712, 2017 Feb 28.
Article
em En
| MEDLINE
| ID: mdl-28197589
ABSTRACT
A new imidooxonitridophosphate AlP6O3x(NH)3-3xN9 with x ≈ 0.33 was synthesized under high-pressure high-temperature conditions. The crystal structure determination of the microcrystalline product involved a combination of electron microscopy, synchrotron X-ray diffraction and solid-state NMR. In the solid there are discrete AlN6 octahedra that interconnect imidophosphate layers. The network topology is unprecedented but is related to other nitride structures.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2017
Tipo de documento:
Article