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B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane.
Ding, Fangwei; Zhang, Yiliang; Zhao, Rong; Jiang, Yanqiu; Bao, Robert Li-Yuan; Lin, Kaifeng; Shi, Lei.
Afiliação
  • Ding F; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn and Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.
  • Zhang Y; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn and Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.
  • Zhao R; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn and Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.
  • Jiang Y; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn.
  • Bao RL; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn and Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.
  • Lin K; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn.
  • Shi L; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. lshi@hit.edu.cn and Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.
Chem Commun (Camb) ; 53(66): 9262-9264, 2017 Aug 25.
Article em En | MEDLINE | ID: mdl-28771256
ABSTRACT
A transition-metal-free method for the B(C6F5)3-promoted hydrogenations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2017 Tipo de documento: Article