Rhodium-Catalyzed Direct Ortho C-H Arylation Using Ketone as Directing Group with Boron Reagent.
Org Lett
; 19(21): 5940-5943, 2017 11 03.
Article
em En
| MEDLINE
| ID: mdl-29048909
A general method for selective ortho C-H arylation of ketone, with boron reagent enabled by rhodium complexes with excellent yields, is developed. The transformation is characterized by the use of air-stable Rh catalyst, high monoarylation selectivity, and excellent yields of most of the substrates.
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01-internacional
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MEDLINE
Idioma:
En
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Org Lett
Ano de publicação:
2017
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Article