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Electrosynthesis of Trisubstituted 2-Oxazolines via Dehydrogenative Cyclization of ß-Amino Arylketones.
Wang, Huiqiao; Zhang, Jinjin; Tan, Jiajing; Xin, Lilan; Li, Yaping; Zhang, Sheng; Xu, Kun.
Afiliação
  • Wang H; Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering , Nanyang Normal University , Nanyang , Henan 473061 , P. R. China.
  • Zhang J; Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering , Nanyang Normal University , Nanyang , Henan 473061 , P. R. China.
  • Tan J; Department of Organic Chemistry, Faculty of Science , Beijing University of Chemical Technology , Beijing 100029 , China.
  • Xin L; Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering , Nanyang Normal University , Nanyang , Henan 473061 , P. R. China.
  • Li Y; Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering , Nanyang Normal University , Nanyang , Henan 473061 , P. R. China.
  • Zhang S; Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering , Nanyang Normal University , Nanyang , Henan 473061 , P. R. China.
  • Xu K; Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering , Nanyang Normal University , Nanyang , Henan 473061 , P. R. China.
Org Lett ; 20(9): 2505-2508, 2018 05 04.
Article em En | MEDLINE | ID: mdl-29664646
ABSTRACT
An electrochemically intramolecular functionalization of C(sp3)-H bonds with masked oxygen nucleophiles was developed. With KI as the catalyst and electrolyte, diverse trisubstituted 2-oxazolines were constructed in good to excellent yields. This newly developed electrochemical dehydrogenative approach features external oxidant-free and additive-free conditions.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Ano de publicação: 2018 Tipo de documento: Article