Removal of sulfamethoxazole, ibuprofen and nitrobenzene by UV and UV/chlorine processes: A comparative evaluation of 275â¯nm LED-UV and 254â¯nm LP-UV.
Sci Total Environ
; 637-638: 1351-1357, 2018 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-29801227
ABSTRACT
The aim of this study is to evaluate the micropollutant removal capacity of a 275â¯nm light-emitting diode (LED)-UV/chlorine system. The sulfamethoxazole, ibuprofen, and nitrobenzene removal efficiencies of this system were compared with those of a conventional 254â¯nm low-pressure (LP)-UV system as a function of the UV dose. In a direct photolysis system, the photon reactivity of sulfamethoxazole is higher than that of nitrobenzene and ibuprofen at both wavelengths. The molar absorption coefficients and quantum yields of each micropollutant were as follows sulfamethoxazole (εSMX, 275 nmprotonatedâ¯=â¯17,527â¯M-1â¯cm-1, ΦSMX, 275 nmprotonatedâ¯=â¯0.239, εSMX, 275 nmdeprotonatedâ¯=â¯8430â¯M-1â¯cm-1, and ΦSMX, 275 nmdeprotonatedâ¯=â¯0.026), nitrobenzene (εNB, 275 nmâ¯=â¯7176â¯M-1â¯cm-1 and ΦNB, 275 nmâ¯=â¯0.057), and ibuprofen (εNB, 275 nmâ¯=â¯200â¯M-1â¯cm-1 and ΦIBF, 275 nmâ¯=â¯0.067). The photon reactivity of chlorine species, i.e., HOCl and OCl-, were determined at 275â¯nm (εHOCl, 275 nmâ¯=â¯28â¯M-1â¯cm-1, ΦHOCl, 275 nmâ¯=â¯1.97, εOCl-, 275 nmâ¯=â¯245â¯M-1â¯cm-1, and ΦOCl-, 275 nmâ¯=â¯0.8), which indicate that the decomposition rate of OCl- is higher and that of HOCl is lower by 275â¯nm photolysis than that by 254â¯nm photolysis (εHOCl, 254 nmâ¯=â¯60â¯M-1â¯cm-1, ΦHOCl, 254 nmâ¯=â¯1.46, εOCl-, 254 nmâ¯=â¯58â¯M-1â¯cm-1, and ΦOCl-, 254 nmâ¯=â¯1.11). In the UV/chlorine system, the removal rates of ibuprofen and nitrobenzene were increased by the formation of OH and reactive chlorine species. The 275-nm LED-UV/chlorine system has higher radical yields at pHâ¯7 and 8 than the 254â¯nm LP-UV/chlorine system.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Sulfametoxazol
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Poluentes Químicos da Água
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Cloro
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Ibuprofeno
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Purificação da Água
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Nitrobenzenos
Idioma:
En
Revista:
Sci Total Environ
Ano de publicação:
2018
Tipo de documento:
Article