Your browser doesn't support javascript.
loading
Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework.
Agou, Tomohiro; Wada, Nao; Fujisawa, Kiyoshi; Hosoya, Takaaki; Mizuhata, Yoshiyuki; Tokitoh, Norihiro; Fukumoto, Hiroki; Kubota, Toshio.
Afiliação
  • Agou T; Department of Quantum Beam Science, Graduate School of Science and Engineering , Ibaraki University , 4-12-1, Nakanarusawa , Hitachi , Ibaraki 316-8511 , Japan.
  • Wada N; Department of Quantum Beam Science, Graduate School of Science and Engineering , Ibaraki University , 4-12-1, Nakanarusawa , Hitachi , Ibaraki 316-8511 , Japan.
  • Fujisawa K; Department of Chemistry, Faculty of Science , Ibaraki University , Mito , Ibaraki 310-8512 , Japan.
  • Hosoya T; Department of Quantum Beam Science, Graduate School of Science and Engineering , Ibaraki University , 4-12-1, Nakanarusawa , Hitachi , Ibaraki 316-8511 , Japan.
  • Mizuhata Y; Institute for Chemical Research , Kyoto University , Gokasho, Uji , Kyoto 611-0011 , Japan.
  • Tokitoh N; Institute for Chemical Research , Kyoto University , Gokasho, Uji , Kyoto 611-0011 , Japan.
  • Fukumoto H; Department of Quantum Beam Science, Graduate School of Science and Engineering , Ibaraki University , 4-12-1, Nakanarusawa , Hitachi , Ibaraki 316-8511 , Japan.
  • Kubota T; Department of Quantum Beam Science, Graduate School of Science and Engineering , Ibaraki University , 4-12-1, Nakanarusawa , Hitachi , Ibaraki 316-8511 , Japan.
Inorg Chem ; 57(15): 9105-9114, 2018 Aug 06.
Article em En | MEDLINE | ID: mdl-29984577
ABSTRACT
Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via UV/vis absorption studies and crystal structure analysis. Successful catalytic application of the Au(I) complex for alkyne hydration reactions was investigated.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2018 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2018 Tipo de documento: Article