Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework.
Inorg Chem
; 57(15): 9105-9114, 2018 Aug 06.
Article
em En
| MEDLINE
| ID: mdl-29984577
ABSTRACT
Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via UV/vis absorption studies and crystal structure analysis. Successful catalytic application of the Au(I) complex for alkyne hydration reactions was investigated.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2018
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Article