A Novel Non-Enzymatic Electrochemical Hydrogen Peroxide Sensor Based on a Metal-Organic Framework/Carbon Nanofiber Composite.

ABSTRACT

A co-based porous metal-organic framework (MOF) of zeolitic imidazolate framework-67 (ZIF-67) and carbon nanofibers (CNFs) was utilized to prepare a ZIF-67/CNFs composite via a one-pot synthesis method. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD) were employed to investigate the morphology, structure, and composition of the resulting composite. A novel high-performance non-enzymatic electrochemical sensor was constructed based on the ZIF-67/CNFs composite. The ZIF-67/CNFs based sensor exhibited enhanced electrocatalytic activity towards H2O2 compared to a pure ZIF-67-based sensor, due to the synergistic effects of ZIF-67 and CNFs. Meanwhile, chronoamperometry was utilized to explore the detection performance of the sensor. Results showed the sensor displayed high-efficiency electrocatalysis towards H2O2 with a detection limit of 0.62 µM (S/N = 3), a sensitivity of 323 µA mM-1 cm-2, a linear range from 0.0025 to 0.19 mM, as well as satisfactory selectivity and long-term stability. Furthermore, the sensor demonstrated its application potential in the detection of H2O2 in food.