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Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy-O2 batteries.
Ma, Jin-Ling; Meng, Fan-Lu; Yu, Yue; Liu, Da-Peng; Yan, Jun-Min; Zhang, Yu; Zhang, Xin-Bo; Jiang, Qing.
Afiliação
  • Ma JL; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China.
  • Meng FL; Key Laboratory of Automobile Materials, Ministry of Education, and Department of Materials Science and Engineering, Jilin University, Changchun, Jilin, China.
  • Yu Y; University of Chinese Academy of Sciences, Beijing, China.
  • Liu DP; Key Laboratory of Automobile Materials, Ministry of Education, and Department of Materials Science and Engineering, Jilin University, Changchun, Jilin, China.
  • Yan JM; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China.
  • Zhang Y; University of Science and Technology of China, Hefei, Anhui, China.
  • Zhang XB; Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education School of Chemistry Beihang University Beijing, Beijing, China.
  • Jiang Q; Key Laboratory of Automobile Materials, Ministry of Education, and Department of Materials Science and Engineering, Jilin University, Changchun, Jilin, China. junminyan@jlu.edu.cn.
Nat Chem ; 11(1): 64-70, 2019 01.
Article em En | MEDLINE | ID: mdl-30420775
ABSTRACT
Rechargeable aprotic alkali metal (Li or Na)-O2 batteries are the subject of great interest because of their high theoretical specific energy. However, the growth of dendrites and cracks at the Li or Na anode, as well as their corrosive oxidation lead to poor cycling stability and safety issues. Understanding the mechanism and improving Li/Na-ion plating and stripping electrochemistry are therefore essential to realizing their technological potential. Here, we report how the use of a Li-Na alloy anode and an electrolyte additive realizes an aprotic bimetal Li-Na alloy-O2 battery with improved cycling stability. Electrochemical investigations show that stripping and plating of Li and Na and the robust and flexible passivation film formed in situ (by 1,3-dioxolane additive reacting with the Li-Na alloy) suppress dendrite and buffer alloy anode volume expansion and thus prevent cracking, avoiding electrolyte consumption and ensuring high electron transport efficiency and continued electrochemical reactions.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Nat Chem Ano de publicação: 2019 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Nat Chem Ano de publicação: 2019 Tipo de documento: Article