A Highly Ionic Conductive, Healable, and Adhesive Polysiloxane-Supported Ionogel.
Macromol Rapid Commun
; 40(7): e1800776, 2019 Apr.
Article
em En
| MEDLINE
| ID: mdl-30653789
ABSTRACT
A new kind of polysiloxane-supported ionogel is successfully designed via locking ionic liquids (ILs), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][Tf2 N]), into poly(aminopropyl-methylsiloxane) (PAPMS) grafted with [2-(methacryloyloxy)ethyl] trimethylammonium chloride (METAC) in the presence of tannic acid (TA). The novel ionogel exhibits good mechanical and recovery properties, as well as high ionic conductivity (1.19 mS cm-1 ) at 25 °C. In addition, the totally physical dual-crosslinked network based on ionic aggregates among METAC and the hydrogen bonds between PAPMS and TA provides excellent self-healing ability, which allows the damaged ionogel to almost completely heal (≈83%) in 12 h at room temperature. Interestingly, the obtained ionogel also shows satisfactory adhesive behavior to various solid materials. Moreover, this novel ionogel can maintain its high ionic conductivity and recovery property even at subzero temperatures. Therefore, this polysiloxane-supported ionogel is anticipated to be advantageous in flexible electronic devices such as sensors and supercapacitors, even at low temperatures.
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01-internacional
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MEDLINE
Assunto principal:
Siloxanas
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Idioma:
En
Revista:
Macromol Rapid Commun
Ano de publicação:
2019
Tipo de documento:
Article