Electron Highways into Nanochannels of Covalent Organic Frameworks for High Electrical Conductivity and Energy Storage.
ACS Appl Mater Interfaces
; 11(8): 7661-7665, 2019 Feb 27.
Article
em En
| MEDLINE
| ID: mdl-30702269
ABSTRACT
To enhance the electron transfer within the covalent organic frameworks (COFs), we obtained a nanocomposite of conductive poly(3,4-ethylenedioxythiophene) (PEDOT) and redox-active AQ-COF by performing a facile in situ solid-state polymerization inside the nanochannels of COFs. The PEDOT chains functioned like electron highways within the nanochannels, resulting in a PEDOT@AQ-COF nanocomposite with an excellent electrical conductivity of 1.1 S cm-1 and a remarkably improved performance in faradaic energy storage. The all-organic PEDOT@AQ-COF electrode showed specific capacitance as high as 1663 F g-1 (at 1 A g-1), ultrafast charge/discharge rate performance (998 F g-1 at 500 A g-1), and excellent stability for 10â¯000 cycles. This research demonstrates a promising strategy for increasing the conductivity of COF-based materials and broadening their applications.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Ano de publicação:
2019
Tipo de documento:
Article