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Ester Formation via Symbiotic Activation Utilizing Trichloroacetimidate Electrophiles.
Mahajani, Nivedita S; Meador, Rowan I L; Smith, Tomas J; Canarelli, Sarah E; Adhikari, Arijit A; Shah, Jigisha P; Russo, Christopher M; Wallach, Daniel R; Howard, Kyle T; Millimaci, Alexandra M; Chisholm, John D.
Afiliação
  • Mahajani NS; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Meador RIL; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Smith TJ; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Canarelli SE; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Adhikari AA; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Shah JP; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Russo CM; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Wallach DR; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Howard KT; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Millimaci AM; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
  • Chisholm JD; Department of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
J Org Chem ; 84(12): 7871-7882, 2019 06 21.
Article em En | MEDLINE | ID: mdl-31117564
ABSTRACT
Trichloroacetimidates are useful reagents for the synthesis of esters under mild conditions that do not require an exogenous promoter. These conditions avoid the undesired decomposition of substrates with sensitive functional groups that are often observed with the use of strong Lewis or Brønsted acids. With heating, these reactions have been extended to benzyl esters without electron-donating groups. These inexpensive and convenient methods should find application in the formation of esters in complex substrates.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Elétrons / Ésteres / Cloroacetatos / Acetamidas Idioma: En Revista: J Org Chem Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Elétrons / Ésteres / Cloroacetatos / Acetamidas Idioma: En Revista: J Org Chem Ano de publicação: 2019 Tipo de documento: Article