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Intriguing Near-Infrared Solid-State Luminescence of Binuclear Silver(I) Complexes Based on Pyridylphospholane Scaffolds.
Shamsieva, Aliia V; Musina, Elvira I; Gerasimova, Tatiana P; Fayzullin, Robert R; Kolesnikov, Ilya E; Samigullina, Aida I; Katsyuba, Sergey A; Karasik, Andrey A; Sinyashin, Oleg G.
Afiliação
  • Shamsieva AV; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Musina EI; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Gerasimova TP; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Fayzullin RR; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Kolesnikov IE; Center for Optical and Laser Materials Research , Research Park of St. Petersburg State University , Ulianovskaya Street 5 , 198504 St. Petersburg , Russian Federation.
  • Samigullina AI; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Katsyuba SA; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Karasik AA; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
  • Sinyashin OG; Arbuzov Institute of Organic and Physical Chemistry , FRC Kazan Scientific Center, Russian Academy of Sciences , Arbuzov Street 8 , 420088 Kazan , Russian Federation.
Inorg Chem ; 58(12): 7698-7704, 2019 Jun 17.
Article em En | MEDLINE | ID: mdl-31144500
ABSTRACT
A series of novel charged disilver(I) complexes with pyridyl-containing phospholanes was synthesized. These complexes were characterized using a range of spectroscopic techniques and single-crystal and powder X-ray diffraction. The complexes demonstrate solid-state near-infrared (NIR) luminescence (765-902 nm) that is unique for dinuclear AgI complexes. Combined spectroscopic/quantum chemical analysis suggests that the NIR luminescence of complexes 4-6 in the solid state is mainly due to crystal packing effects.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2019 Tipo de documento: Article