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The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis.
Pichon, Delphine; Soleilhavoup, Michele; Morvan, Jennifer; Junor, Glen P; Vives, Thomas; Crévisy, Christophe; Lavallo, Vincent; Campagne, Jean-Marc; Mauduit, Marc; Jazzar, Rodolphe; Bertrand, Guy.
Afiliação
  • Pichon D; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Soleilhavoup M; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Morvan J; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Junor GP; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Vives T; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Crévisy C; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Lavallo V; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Campagne JM; Institut Charles Gerhardt , UMR 5253 CNRS-UM2-UM1-ENSCM , 8 Rue l'Ecole Normale , 34296 Montpellier , France.
  • Mauduit M; Ecole Nationale Supérieure de Chimie de Rennes , Univ Rennes , CNRS , ISCR - UMR 6226 , F-35000 Rennes , France . Email: marc.mauduit@ensc-rennes.fr.
  • Jazzar R; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
  • Bertrand G; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555) , University of California San Diego , La Jolla , California 92093-0353 , USA . Email: rjazzar@ucsd.edu ; Email: gbertrand@ucsd.edu.
Chem Sci ; 10(33): 7807-7811, 2019 Sep 07.
Article em En | MEDLINE | ID: mdl-31588330
The popularity of NHCs in transition metal catalysis has prompted the development of chiral versions as electron-rich neutral stereodirecting ancillary ligands for enantioselective transformations. Herein we demonstrate that cyclic (alkyl)(amino)carbene (CAAC) ligands can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbenes.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Sci Ano de publicação: 2019 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Sci Ano de publicação: 2019 Tipo de documento: Article