Electrochemical dehydrogenative cross-coupling of xanthenes with ketones.
Chem Commun (Camb)
; 56(55): 7585-7588, 2020 Jul 14.
Article
em En
| MEDLINE
| ID: mdl-32510076
ABSTRACT
A new external oxidant-free electrochemical dehydrogenative cross-coupling of xanthenes and ketones for the preparation of functionalized 9-alkyl-9H-xanthenes was developed. This method enables the formation of a new C(sp3)-C(sp3) bond through release of H2 as the major byproduct at room temperature, and features mild conditions, high atom economy, excellent functional-group tolerance, scalability and facile applications in pharmaceutical chemistry.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2020
Tipo de documento:
Article