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Copper-Catalyzed Cross-Coupling between Alkyl (Pseudo)halides and Bicyclopentyl Grignard Reagents.
Andersen, Claire; Ferey, Vincent; Daumas, Marc; Bernardelli, Patrick; Guérinot, Amandine; Cossy, Janine.
Afiliação
  • Andersen C; Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL University, 10 rue Vauquelin, 75005 Paris, France.
  • Ferey V; Sanofi R&D, 371 rue du Professeur Joseph Blayac, 34080 Montpellier, France.
  • Daumas M; Sanofi Chimie, Route d'Avignon, 30390 Aramon, France.
  • Bernardelli P; Sanofi R&D, 1 avenue Pierre Brossolette, 91380 Chilly-Mazarin, France.
  • Guérinot A; Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL University, 10 rue Vauquelin, 75005 Paris, France.
  • Cossy J; Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL University, 10 rue Vauquelin, 75005 Paris, France.
Org Lett ; 22(15): 6021-6025, 2020 Aug 07.
Article em En | MEDLINE | ID: mdl-32672465
The development of a copper-catalyzed cross-coupling between primary and secondary (pseudo)halides and bicyclopentyl Grignard reagents is reported. Highly strained bicyclopentanes can be cross-coupled with a large panel of primary alkyl mesylates and secondary alkyl iodides. The catalytic system is simple and cheap, and the reaction is general and chemoselective.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Ano de publicação: 2020 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Ano de publicação: 2020 Tipo de documento: Article