Ligand Conformational Flexibility Enables Enantioselective Tertiary C-B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration.

Shao, Huiling; Chakrabarty, Suman; Qi, Xiaotian; Takacs, James M; Liu, Peng

Shao, Huiling; Chakrabarty, Suman; Qi, Xiaotian; Takacs, James M; Liu, Peng.

Afiliação

Shao H; Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, United States.
Chakrabarty S; Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, United States.
Qi X; Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588, United States.
Takacs JM; Life Sciences Institute, University of Michigan, Ann Arbor, Michigan 48109, United States.
Liu P; Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, United States.

J Am Chem Soc ; 143(12): 4801-4808, 2021 03 31.

Article em En | MEDLINE | ID: mdl-33750118

Assuntos

Alcenos/química; Boranos/síntese química; Organofosfonatos/química; Boranos/química; Catálise; Ligantes; Conformação Molecular; Estereoisomerismo

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Boranos / Alcenos / Organofosfonatos Idioma: En Revista: J Am Chem Soc Ano de publicação: 2021 Tipo de documento: Article

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