In situ phase transformation of polytypic zinc-blende/wurtzite copper indium sulfide via a facile polyol method to boost visible-light photocatalytic performance.

ABSTRACT

A zinc-blende/wurtzite (ZB/WZ) copper indium sulfide (CuInS2/CIS) polymorph with high visible-light absorption ability and high charge separation rate was developed by using a facile polyol method. Results showed that when thioacetamide served as a sulfur precursor, the crystalline phase of CIS was zinc-blende. Meanwhile, when thiourea served as a sulfur precursor, the crystalline phase of CIS was wurtzite, which exhibited good photocatalytic acid red 1 (AR1) dye decolorization efficiency. When the precursor/ethylene glycol ratio was 1/50-7/50, the AR1 decolorization efficiency followed the order T-5-CIS > T-7-CIS > T-3-CIS > T-1-CIS, and the TOC removal efficiency of T-5-CIS was 45.7%. The PL and EIS analyses indicated that T-5-CIS showed the highest charge separation rate. Mott-Schottky analysis demonstrated that the remarkably enhanced photocatalytic decolorization rate was ascribed to the stronger reduction potential of CIS with the mixed ZB/WZ phases and the redox potential difference between the ZB and WZ phases, leading to a good oxidation ability and charge separation. The results indicated that O2- was the main reactive specie in this study, and this study provided a potential photocatalyst in the treatment of dye wastewater.