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Ruthenium-catalyzed C-H amination of aroylsilanes.
Yu, Feifei; Shen, Wenzhou; Sun, Yaling; Liao, Yilei; Jin, Shuqi; Lu, Xiunan; He, Rui; Zhong, Liangjun; Zhong, Guofu; Zhang, Jian.
Afiliação
  • Yu F; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • Shen W; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • Sun Y; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • Liao Y; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • Jin S; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • Lu X; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • He R; Department of Stomatology, The Affiliated Hospital of Hangzhou Normal University, Hangzhou Normal University, Hangzhou, 310015, China. zymdxx@163.com heruiminli@sina.com.
  • Zhong L; Department of Stomatology, The Affiliated Hospital of Hangzhou Normal University, Hangzhou Normal University, Hangzhou, 310015, China. zymdxx@163.com heruiminli@sina.com.
  • Zhong G; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn.
  • Zhang J; College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. zhangjian@hznu.edu.cn and Department of Stomatology, The Affiliated Hospital of Hangzhou Normal University, Hangzhou Normal University, Hangzhou, 310015, China. zymdxx@163.com heruiminli@sin
Org Biomol Chem ; 19(28): 6313-6321, 2021 07 21.
Article em En | MEDLINE | ID: mdl-34212972
Acylsilane represents a valuable synthon in synthetic chemistry. We report on ruthenium(ii)-catalyzed ortho-C-H amination of aroylsilanes to provide facile access to synthetically useful imidobenzoylsilanes and tosyl-amidobenzoylsilanes. The protocols, with broad substrate scope and excellent functional group tolerance, are enabled with the weak chelation-assistance of acylsilane via C-H cyclometallation.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Ano de publicação: 2021 Tipo de documento: Article