Interfacial engineering coupling with tailored oxygen vacancies in Co2Mn2O4 spinel hollow nanofiber for catalytic phenol removal.

ABSTRACT

Herein, one-dimensional Co2Mn2O4 (CMO) hollow nanofibers with a general spinel structure were constructed by electrospinning and tunning thermal-driven procedures. The resultant catalyst was endowed with appreciable active interfacial engineering effect, which revealed improved peroxymonosulfate (PMS) activation efficiency in catalytic phenol degradation with nearly 12.9 folds increment in reaction rate constant compared to the hydrothermally synthesized counterpart. Besides, tailored oxygen-vacancy sites including chemical environment and contents in the bimetallic spinel were rationally validated compared to the monometal spinel counterparts. The improved catalytic phenol degradation by reactive-oxidative-species (ROS) from PMS was well correlated with the more active Co(II) and Mn(II) species, reactive active oxygen-vacancy and the interfacial engineering effect in the CMO catalyst. These correlations were comprehensively demonstrated by various characterization techniques, catalytic results, and Density-Functional-Theoretical (DFT) calculations of the adsorption and activation of PMS. Besides, the results revealed that the specific content of cobalt species in the structural unit of the Co2Mn2O4 spinel resulting from the optimized thermal treatment could further improve the catalytic activity by the intermetallic synergy along with the beneficial electron transfer cycles. This work provides a practical understanding of the improvement of interfacial systems in catalysis efficiency and environmental remediation.