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Photoinduced remote regioselective radical alkynylation of unactivated C-H bonds.
Hu, Qu-Ping; Liu, Yu-Tao; Liu, Yong-Ze; Pan, Fei.
Afiliação
  • Hu QP; College of Chemistry and Materials Science, Sichuan Normal University, 5 Jingan Road, Chengdu 610068, P. R. China. feipan@sicnu.edu.cn.
  • Liu YT; College of Chemistry and Materials Science, Sichuan Normal University, 5 Jingan Road, Chengdu 610068, P. R. China. feipan@sicnu.edu.cn.
  • Liu YZ; College of Chemistry and Materials Science, Sichuan Normal University, 5 Jingan Road, Chengdu 610068, P. R. China. feipan@sicnu.edu.cn.
  • Pan F; College of Chemistry and Materials Science, Sichuan Normal University, 5 Jingan Road, Chengdu 610068, P. R. China. feipan@sicnu.edu.cn.
Chem Commun (Camb) ; 58(14): 2295-2298, 2022 Feb 15.
Article em En | MEDLINE | ID: mdl-35075463
ABSTRACT
A method for the remote regioselective alkynylation of unactivated C(sp3)-H bonds in diverse aliphatic amides by photogenerated amidyl radicals has been developed. The site-selectivity is dominated via a 1,5-hydrogen atom transfer (HAT) process of the amide. Mild reaction conditions and high regioselectivity are demonstrated in this methodology.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2022 Tipo de documento: Article