Photoinduced remote regioselective radical alkynylation of unactivated C-H bonds.
Chem Commun (Camb)
; 58(14): 2295-2298, 2022 Feb 15.
Article
em En
| MEDLINE
| ID: mdl-35075463
ABSTRACT
A method for the remote regioselective alkynylation of unactivated C(sp3)-H bonds in diverse aliphatic amides by photogenerated amidyl radicals has been developed. The site-selectivity is dominated via a 1,5-hydrogen atom transfer (HAT) process of the amide. Mild reaction conditions and high regioselectivity are demonstrated in this methodology.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2022
Tipo de documento:
Article