Your browser doesn't support javascript.
loading
Tropo(thio)ne-embedded homoHPHACs: does the tropylium cation induce global antiaromaticity in expanded hexapyrrolohexaazacoronene?
Takase, Masayoshi; Ueno, Atsushi; Oki, Kosuke; Matsumoto, Hiroki; Mori, Shigeki; Okujima, Tetsuo; Uno, Hidemitsu.
Afiliação
  • Takase M; Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan. takase.masayoshi.ry@ehime-u.ac.jp.
  • Ueno A; Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan. takase.masayoshi.ry@ehime-u.ac.jp.
  • Oki K; Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan. takase.masayoshi.ry@ehime-u.ac.jp.
  • Matsumoto H; Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan. takase.masayoshi.ry@ehime-u.ac.jp.
  • Mori S; Advanced Research Support Center, Ehime University, Matsuyama 790-8577, Japan.
  • Okujima T; Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan. takase.masayoshi.ry@ehime-u.ac.jp.
  • Uno H; Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan. takase.masayoshi.ry@ehime-u.ac.jp.
Chem Commun (Camb) ; 58(20): 3366-3369, 2022 Mar 08.
Article em En | MEDLINE | ID: mdl-35188504
Tropo(thio)ne-embedded homoHPHACs and their dications were synthesised by an electrophilic annulation of secoHPHAC and successive oxidation. 13C NMR spectra of the dications represented global 22π homoaromaticity via homoconjugation, while alkylation of a thiocarbonyl-bridged homoHPHAC produced a 24π antiaromatic monocation.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2022 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2022 Tipo de documento: Article