Confined Lithium Deposition Triggered by an Integrated Gradient Scaffold for a Lithium-Metal Anode.
ACS Appl Mater Interfaces
; 14(15): 17539-17546, 2022 Apr 20.
Article
em En
| MEDLINE
| ID: mdl-35403422
ABSTRACT
Constructing a composite lithium anode with a rational structure has been considered as an effective approach to regulate and relieve the tough problems of a sparkling Li anode. However, the potential short circuits risk that Li deposition at the surface of the framework has not yet been resolved. Here, we present a simple regulating-deposition strategy to guide the preferentially bottom-up deposition/growth of Li. The triple-gradient structure of modified porous copper with electrical passivation (top) and chemical activation (bottom) shows significant improvements in the morphological stability and electrochemical performance. Meanwhile, the in situ generation of Li2Se can as an advanced artificial SEI layer be devoted to homogeneous Li plating/stripping. As a result, the composite anode exhibits a long-term cycling over 250 cycles with a high average CE of 98.2% at 1 mA cm-2. Furthermore, a capacity retention of 94.4% in full cells can be achieved when pairing with LiFePO4 as the cathode. These results ensure a bright direction for developing high-performance Li metal anodes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Ano de publicação:
2022
Tipo de documento:
Article