Flexible poly(vinylidene fluoride-co-hexafluoropropylene)-based gel polymer electrolyte for high-performance lithium-ion batteries.
RSC Adv
; 11(20): 11943-11951, 2021 Mar 23.
Article
em En
| MEDLINE
| ID: mdl-35423739
ABSTRACT
Gel polymer electrolytes (GPEs) have attracted ever-increasing attention in Li-ion batteries, due to their great thermal stability and excellent electrochemical performance. Here, a flexible poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)-based GPE doped with an appropriate proportion of the PEO and SiO2 is developed through a universal immersion precipitation method. This porous PVDF-HFP-PEO-SiO2 GPE with high ionic conductivity and lithium-ion transference number (t Li+ ) can enhance the electrochemical performance of LiFePO4 cells, leading to superior rate capability and excellent cycling stability. Moreover, the PVDF-HFP-PEO-SiO2 GPE effectively inhibits the lithium dendrite growth, thereby improving the safety of Li-ion batteries. In view of the simplicity in using the gel polymer electrolyte, it is believed that this novel GPE can be used as a potential candidate for high-performance Li-ion batteries.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
RSC Adv
Ano de publicação:
2021
Tipo de documento:
Article