A neutral analogue of a phosphamethine cyanine.

Cicac-Hudi, Mario; Kaaz, Manuel; Birchall, Nicholas; Nieger, Martin; Gudat, Dietrich

Cicac-Hudi, Mario; Kaaz, Manuel; Birchall, Nicholas; Nieger, Martin; Gudat, Dietrich.

Afiliação

Cicac-Hudi M; Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany. gudat@iac.uni-stuttgart.de.
Kaaz M; Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany. gudat@iac.uni-stuttgart.de.
Birchall N; Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany. gudat@iac.uni-stuttgart.de.
Nieger M; Department of Chemistry, University of Helsinki, P.O. Box 55, 00014 University of Helsinki, Finland.
Gudat D; Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany. gudat@iac.uni-stuttgart.de.

Dalton Trans ; 51(17): 6533-6536, 2022 May 03.

Article em En | MEDLINE | ID: mdl-35438112

ABSTRACT

ABSTRACT

Reaction of an imidazolio-phosphide with an N-heterocyclic bromo-borane and NaH afforded a neutral analogue of a phosphamethine cyanine cation. DFT studies were used to analyse the dative bonding across P-C/B bonds and the conformational preferences and imply that the observed conformation is imposed by sterics.

Assuntos

Boranos; Quinolinas; Boranos/química; Cátions; Conformação Molecular

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Quinolinas / Boranos Idioma: En Revista: Dalton Trans Ano de publicação: 2022 Tipo de documento: Article

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