High quantum yield photochemical water oxidation using a water-soluble cobalt phthalocyanine as a homogenous catalyst.

Nakazono, Takashi; Amino, Nagisa; Matsuda, Risa; Sugawara, Daichi; Wada, Tohru

Nakazono, Takashi; Amino, Nagisa; Matsuda, Risa; Sugawara, Daichi; Wada, Tohru.

Afiliação

Nakazono T; Research Center for Artificial Photosynthesis (ReCAP), Osaka Metropolitan University, 3-3-138, Sumiyoshi-ku, Osaka, 558-8585, Japan. nakazono@omu.ac.jp.
Amino N; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Toshima-ku, Tokyo, 171-8501, Japan.
Matsuda R; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Toshima-ku, Tokyo, 171-8501, Japan.
Sugawara D; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Toshima-ku, Tokyo, 171-8501, Japan.
Wada T; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Toshima-ku, Tokyo, 171-8501, Japan.

Chem Commun (Camb) ; 58(55): 7674-7677, 2022 Jul 07.

Article em En | MEDLINE | ID: mdl-35726648

ABSTRACT

ABSTRACT

We demonstrated high catalytic activity (TON = 670, TOFmax = 2.7 s-1) of a water-soluble cobalt phthalocyanine complex (CoPcTS, PcTS = phthalocyaninetetrasulfonate) for visible light-driven photochemical water oxidation and investigated its reaction mechanism by electrochemical and spectroscopic measurements.

Assuntos

Compostos Organometálicos; Água; Catálise; Cobalto/química; Indóis; Compostos Organometálicos/química; Água/química

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Água Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2022 Tipo de documento: Article

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