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Nitro-Decorated Microporous Covalent Organic Framework (TpPa-NO2) for Selective Separation of C2H4 from a C2H2/C2H4/CO2 Mixture and CO2 Capture.
Xiong, Xiao-Hong; Zhang, Liang; Wang, Wei; Zhu, Neng-Xiu; Qin, Lu-Zhu; Huang, Huan-Feng; Meng, Liu-Li; Xiong, Yang-Yang; Barboiu, Mihail; Fenske, Dieter; Hu, Peng; Wei, Zhang-Wen.
Afiliação
  • Xiong XH; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Zhang L; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Wang W; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Zhu NX; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Qin LZ; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Huang HF; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Meng LL; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Xiong YY; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Barboiu M; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Fenske D; Adaptive Supramolecular Nanosystems Group, Institut Européen des Membranes (IEM), University of Montpellier, Montpellier 34000, France.
  • Hu P; MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China.
  • Wei ZW; Institut für Nanotechnologie (INT) und Karlsruher Nano-Micro-Facility (KNMF), Karlsruher Institut für Technologie (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany.
ACS Appl Mater Interfaces ; 14(28): 32105-32111, 2022 Jul 20.
Article em En | MEDLINE | ID: mdl-35791739
ABSTRACT
A nitro-decorated microporous covalent organic framework, TpPa-NO2, has been synthesized in a gram scale with a one-pot reaction. It can effectively selectively separate C2H4 from a C2H2/C2H4/CO2 mixture and capture CO2 from CO2/N2 based on ideal adsorption solution theory calculations and transient breakthrough experiments. Theoretical calculations illustrated that the hydrogen atoms of imine bonds, carbonyl oxygen, and nitro group show high affinity toward C2H2 and CO2, playing vital roles in efficient separation.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Ano de publicação: 2022 Tipo de documento: Article