Iron and zinc porphyrin linked MoO(dithiolene) complexes in relevance to electron transfer between Mo-cofactor and cytochrome b5 in sulfite oxidase.
Dalton Trans
; 51(33): 12447-12452, 2022 Aug 23.
Article
em En
| MEDLINE
| ID: mdl-35946479
ABSTRACT
Oxo-molybdenum (dithiolene) complexes covalently linked individually to iron and zinc porphyrin have been synthesized to show an electron transfer between the two metal centres in relevance to electron transfer from Mo-cofactor to cytochrome b5 domains in the oxidative half of the catalytic cycle of native sulfite oxidase. This association has been investigated by electrochemical, EPR measurement and X-ray absorbance spectroscopy techniques.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Sulfito Oxidase
Idioma:
En
Revista:
Dalton Trans
Ano de publicação:
2022
Tipo de documento:
Article