Helicenic N-heterocyclic carbene copper(I) complex displaying circularly polarized blue fluorescence.
Dalton Trans
; 51(40): 15571-15578, 2022 Oct 18.
Article
em En
| MEDLINE
| ID: mdl-36169005
ABSTRACT
Enantiopure copper(I) chloride complexes bearing a monodentate N-(carbo[6]helicenyl)-NHC ligand have been prepared and characterized experimentally and computationally. Their high stability enables the stereochemistry to be probed by X-ray crystallography and NMR spectroscopy. The resolved enantiomeric complexes emit circularly polarized blue fluorescence with glum â¼1.3 × 10-3 in solution. The photophysical and chiroptical properties of these systems, with their helicene-centred origin, are similar to those of the organic helicene-benzimidazole precursor proligand, although the reverse axial chirality configuration is preferentially observed for the complex compared to the ligand.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Cobre
/
Metano
Idioma:
En
Revista:
Dalton Trans
Ano de publicação:
2022
Tipo de documento:
Article