Synthesis, Post-Functionalization and Properties of Diphosphapentaarenes.
Chemistry
; 29(5): e202202769, 2023 Jan 24.
Article
em En
| MEDLINE
| ID: mdl-36216778
ABSTRACT
Linearly-fused polyarenes are an important class of compounds with high relevance in materials science. While modifying the shape and size represents a common means to fine-tune their properties, the precise placement of heteroatoms is a strategy that is receiving an increasing deal of attention to overcome the intrinsic limitations of all-carbon structures. Thus, linearly-fused diphosphaarenes recently emerged as a novel family of molecules with striking optoelectronic properties and outstanding stability. However, the properties of diphosphaarenes are far from being benchmarked. Herein, we report the synthesis, phosphorus post-functionalization and properties of new diphosphapentaarene derivatives. We describe their synthetic limitations and unveil their potential for optoelectronic applications.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Carbono
/
Ciência dos Materiais
Idioma:
En
Revista:
Chemistry
Ano de publicação:
2023
Tipo de documento:
Article