Electron-compensation: a valid strategy for chemically stabilizing boron-based clusters with hypercoordinate centres.
Chem Commun (Camb)
; 58(94): 13095-13098, 2022 Nov 24.
Article
em En
| MEDLINE
| ID: mdl-36342028
ABSTRACT
To eliminate the chemical instability caused by the electron-deficiency of boron, two types of usual dative π bonds are recommended for compensating boron atoms in the computational design of boron-based clusters having hypercoordinate centres, which can lead to unusually stable targets for synthesis in the condensed phase.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2022
Tipo de documento:
Article