Structural, Magnetic, and Magnetostriction Properties of Flexible, Nanocrystalline CoFe2O4 Films Made by Chemical Processing.

ABSTRACT

We report on the simple, single-step, and cost-effective fabrication, characterization, and performance evaluation of cobalt ferrite (CoFe2O4; CFO) nanocrystalline (NC) thin films on a flexible mica substrate. The chemical solution-based drop-casting method employed to fabricate crystalline CFO films and their characterization was performed by studying the phase formation, surface morphology, and magnetic parameters, while sensor applicability was evaluated using combined magnetic and magnetostrictive properties. X-ray diffraction (XRD) indicates the single-phase and nanocrystalline nature of CFO films, where the crystallite size is ∼60 nm. The optimum conditions employed resulted in CFO NC films with surface particles exhibiting a spherical shape morphology with a homogeneous size distribution, as revealed by scanning electron microscopy analyses. Raman spectroscopic characterization of the chemical bonding indicates all of the active bands that are characteristic of the ferrite phase confirm the spinel structure, which is in agreement with XRD studies. The saturation magnetization (M S) and coercivity (H C), which are extracted from the field-dependent magnetization data, of CFO NC films were found to be 15.8 emu/g and 1.6 kOe, respectively, while the first-order magnetocrystalline anisotropy constant K 1 was ∼1.07 × 106 erg/cm3. The magnetostriction strain curve indicates that the CFO NC films exhibit a strain value of ∼86 ppm at an applied magnetic field of 8 kOe, indicating their suitability for flexible sensor devices.