Determination of distribution coefficients of mercury and gold on selected extraction chromatographic resins - towards an improved separation method of mercury-197 from proton-irradiated gold targets.
J Chromatogr A
; 1688: 463717, 2023 Jan 11.
Article
em En
| MEDLINE
| ID: mdl-36565656
ABSTRACT
Radioisotope mercury-197g (197gHg, half-life 64.14 h) along with its metastable isomer (197mHg, half-life 23.8 h) are potential candidates for targeted Meitner-Auger electron therapy due to their suitable decay properties. Their production can be achieved via proton irradiation of a natural gold target, but the number of studies surrounding their separation from an irradiated gold target is limited. This study focuses on the determination of distribution coefficients (Kd) of gold (III) and mercury (II) on seven extraction chromatographic resins. Mercury Kd were measured by means of radiotracers and Inductively Coupled Plasma Mass Spectrometry (ICP_MS); values obtained from the two methods were generally in good agreement. These results can provide insight on Hg and Au chemistry and aid in the design of improved separation system(s).
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01-internacional
Base de dados:
MEDLINE
Assunto principal:
Mercúrio
Idioma:
En
Revista:
J Chromatogr A
Ano de publicação:
2023
Tipo de documento:
Article