Photochemical Upconversion in Solution: The Role of Oxygen and Magnetic Field Response.
J Phys Chem A
; 127(7): 1794-1800, 2023 Feb 23.
Article
em En
| MEDLINE
| ID: mdl-36753357
ABSTRACT
Upconversion processes effectively convert two or more low energy photons into one higher energy photon, and they have diverse prospective applications in photovoltaics and biomedicine. We focus on two specific mechanisms for photochemical upconversion in solution triplet-triplet annihilation (TTA) and singlet oxygen mediated energy transfer (SOMET). TTA is spin-selective, whereas SOMET is not, so the interplay between these two upconversion mechanisms can be examined via their different magnetic field responses. A kinetic model is developed and applied to explain the different photoluminescence profiles of oxygenated versus deoxygenated systems. From the magnetic field response, the triplet-triplet annihilation rate constant is estimated. The conditions required to maximize upconversion photoluminescence intensity in oxygenated solution are determined, providing a set of design principles to guide molecule choices for robust and air-stable upconversion systems in the future.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Phys Chem A
Ano de publicação:
2023
Tipo de documento:
Article