Electron Transfer Energy and Hydrogen Atom Transfer Energy-Based Linear Free Energy Relationships for Predicting the Rate Constants of Munition Constituent Reduction by Hydroquinones.

Murillo-Gelvez, Jimmy; Hickey, Kevin; Di Toro, Dominic M; Allen, Herbert E; Carbonaro, Richard F; Chiu, Pei C

Murillo-Gelvez, Jimmy; Hickey, Kevin; Di Toro, Dominic M; Allen, Herbert E; Carbonaro, Richard F; Chiu, Pei C.

Afiliação

Murillo-Gelvez J; Department of Civil and Environmental Engineering, University of Delaware, Newark, Delaware 19716, United States.
Hickey K; Department of Civil and Environmental Engineering, University of Delaware, Newark, Delaware 19716, United States.
Di Toro DM; Department of Civil and Environmental Engineering, University of Delaware, Newark, Delaware 19716, United States.
Allen HE; Department of Civil and Environmental Engineering, University of Delaware, Newark, Delaware 19716, United States.
Carbonaro RF; Department of Chemical Engineering, Manhattan College, Riverdale, New York 10471, United States.
Chiu PC; Mutch Associates LLC, Ramsey, New Jersey 07446, United States.

Environ Sci Technol ; 57(13): 5284-5295, 2023 04 04.

Article em En | MEDLINE | ID: mdl-36961098

Assuntos

Hidrogênio; Trinitrotolueno; Elétrons; Hidroquinonas; Transporte de Elétrons

Palavras-chave

electron transfer; hydroquinone; kinetics; linear free energy relationship; munition constituents; nitroaromatic compound; one-electron reduction potential; rate constant; reduction; thermodynamics

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Trinitrotolueno / Hidrogênio Tipo de estudo: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Environ Sci Technol Ano de publicação: 2023 Tipo de documento: Article

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