Your browser doesn't support javascript.
loading
Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF4.
Su, Tong; Wei, Meiqiao; Liu, Hanqing; Fang, Yunshan; Wu, Qiong; Weng, Zhehui; Ling, Jie; Chen, Renjie; Wang, Yulan; Zhao, Xiusha; Ju, Haidong.
Afiliação
  • Su T; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Wei M; Polytechnical Center, Ruili Customs, Yunnan 678600, China.
  • Liu H; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Fang Y; Polytechnical Center, Ruili Customs, Yunnan 678600, China.
  • Wu Q; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Weng Z; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Ling J; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Chen R; Department of Chemistry, University of Alabama in Huntsville, Materials Science Building, John Wright Drive, Huntsville, Alabama 35899, United States.
  • Wang Y; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Zhao X; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
  • Ju H; Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device, School of Chemistry and Chemical Engineering and Innovative Research Teams in Science and Technology in the University of Yunnan Province (IRTSTYN), Kunming University, Yunnan 650214, China.
Inorg Chem ; 62(25): 9882-9891, 2023 Jun 26.
Article em En | MEDLINE | ID: mdl-37314892
ABSTRACT
Two new purely inorganic cationic tellurite networks of Group IB metal-based tetrafluoroborates, namely, [Cu2F(Te2O5)](BF4), 1, and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF4, 2, have been hydrothermally synthesized under mild conditions. The prepared materials have been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR and Raman spectroscopy, SEM-energy-dispersive spectroscopy, UV-vis-NIR diffuse reflectance, magnetic study, and TG analyses. Single-crystal diffraction studies show that both materials have similar cationic Cu/Ag tellurite layers with tetrafluoroborates as interlamellar charge-balancing anions. Magnetic results indicate that [Cu2F(Te2O5)](BF4), 1, exhibits a mainly short-range antiferromagnetic ordering within the 2D layer, and further detailed analysis of magnetic susceptibility analysis confirms a spin-singlet ground state with an energy gap of 85 K.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2023 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2023 Tipo de documento: Article