Narrowband Organic Afterglow via Phosphorescence Förster Resonance Energy Transfer for Multifunctional Applications.

ABSTRACT

Achieving multicolor organic afterglow materials with narrowband emission and high color purity is important in various optoelectronic fields but remains a great challenge. Here, an efficient strategy is presented to obtain narrowband organic afterglow materials via Förster resonance energy transfer from long-lived phosphorescence donors to narrowband fluorescence acceptors in a polyvinyl alcohol matrix. The resulting materials exhibit narrowband emission with a full width at half maximum (FWHM) as small as 23 nm and the longest lifetime of 721.22 ms. Meanwhile, by pairing the appropriate donors and acceptors, multicolor and high color purity afterglow ranging from green to red with the maximum photoluminescence quantum yield of 67.1% are achieved. Moreover, given their long luminescence lifetime, high color purity, and flexibility, the potential applications are demonstrated in high-resolution afterglow displays and dynamic and quick information identification in low-light conditions. This work provides a facile approach for developing multicolor and narrowband afterglow materials as well as expands the features of organic afterglow.