Optically-pure triptycene-based metallomacrocycles and homochiral self-sorting assisted by ladder formation.
Chem Commun (Camb)
; 59(58): 8989-8992, 2023 Jul 18.
Article
em En
| MEDLINE
| ID: mdl-37401157
ABSTRACT
Optically-pure triptycene-based metallomacrocycles are, for the first time, synthesized by the coordination-driven self-assembly of enantiopure triptycene-derived ladder-type bis(benzo[f]isoquinoline) ligands with a cis-platinum(II) complex. A pair of enantiomeric homochiral metallomacrocycles is also produced by the coordination-driven homochiral self-sorting of the corresponding racemic ligands, which relies on the shape-persistent nature of the ladder-structured ligands.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2023
Tipo de documento:
Article