One- and two-electron reductions of a bulky BODIPY compound.
Dalton Trans
; 52(42): 15348-15352, 2023 Oct 31.
Article
em En
| MEDLINE
| ID: mdl-37493621
ABSTRACT
The redox reaction between a bulky BODIPY and a magnesium(I) reducing agent leads to the formal one-electron reduction of the BODIPY, initially generating a dipyrromethene-centred radical compound that dimerises via C-C bond formation. In contrast, reduction with magnesium anthracene leads to the formal two-electron reduction of the BODIPY, resulting in the formation of the corresponding anion.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Ano de publicação:
2023
Tipo de documento:
Article