Design principles for 2D transition metal dichalcogenides toward lithium-sulfur batteries.

ABSTRACT

Lithium-sulfur (Li-S) batteries are regarded as a promising candidate for next-generation energy storage systems owing to their remarkable energy density, resource availability, and environmental benignity. Nevertheless, severe shuttling effect, sluggish redox kinetics, large volumetric expansion, and uncontrollable dendrite growth hamper the practical applications. To address these intractable issues, two-dimensional (2D) transition metal dichalcogenides (TMDs) have emerged expeditiously as an essential material strategy. Herein, this review emphasizes the development and application of 2D TMDs in Li-S batteries. It starts with introducing the fundamentals of Li-S batteries and common synthetic routes of TMDs, followed by summarizing the employment of pristine, hybrid, and defective TMDs in the realm of expediting sulfur chemistry and stabilizing lithium anode. Finally, the development roadmap and possible research directions of TMDs are proposed to offer guidance for the future design of high-performance Li-S batteries.