Directing Intrinsic Chirality in Gold Nanoclusters: Preferential Formation of Stable Enantiopure Clusters in High Yield and Experimentally Unveiling the "Super" Chirality of Au<sub>144</sub>.

Truttmann, Vera; Loxha, Adea; Banu, Rares; Pittenauer, Ernst; Malola, Sami; Matus, María Francisca; Wang, Yuchen; Ploetz, Elizabeth A; Rupprechter, Günther; Bürgi, Thomas; Häkkinen, Hannu; Aikens, Christine; Barrabés, Noelia

Directing Intrinsic Chirality in Gold Nanoclusters: Preferential Formation of Stable Enantiopure Clusters in High Yield and Experimentally Unveiling the "Super" Chirality of Au₁₄₄.

Truttmann, Vera; Loxha, Adea; Banu, Rares; Pittenauer, Ernst; Malola, Sami; Matus, María Francisca; Wang, Yuchen; Ploetz, Elizabeth A; Rupprechter, Günther; Bürgi, Thomas; Häkkinen, Hannu; Aikens, Christine; Barrabés, Noelia.

Afiliação

Truttmann V; Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Loxha A; Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Banu R; Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Pittenauer E; Institute of Chemical Technologies and Analytics, TU Wien, Getreidemarkt 9/E164, 1060 Vienna, Austria.
Malola S; Departments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.
Matus MF; Departments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.
Wang Y; Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States of America.
Ploetz EA; Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States of America.
Rupprechter G; Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Bürgi T; Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva 4, Switzerland.
Häkkinen H; Departments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.
Aikens C; Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States of America.
Barrabés N; Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.

ACS Nano ; 17(20): 20376-20386, 2023 Oct 24.

Article em En | MEDLINE | ID: mdl-37805942

Palavras-chave

chirality; density functional theory; gold; intrinsically chiral; ligand; metal nanoclusters; yield

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Revista: ACS Nano Ano de publicação: 2023 Tipo de documento: Article

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