Your browser doesn't support javascript.
loading
A Layered Aluminophosphate [C17H21N2]3[Al3(PO4)4]·5H2O with Fluorescent Property Derived from Carbazolyl-Modified Template.
Qiu, Jiang-Zhen; Guo, Cheng-Jie; Wu, Qinwu; Liao, Pei-Yu; Deng, Jinyu; Chen, Zhuo-Fan; Yao, Suyang; Lin, Wei-Quan; Jiang, Jiuxing.
Afiliação
  • Qiu JZ; College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, People's Republic of China.
  • Guo CJ; College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, People's Republic of China.
  • Wu Q; College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, People's Republic of China.
  • Liao PY; MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, People's Republic of China.
  • Deng J; College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, People's Republic of China.
  • Chen ZF; College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, People's Republic of China.
  • Yao S; School of Chemistry and Materials Science, Guangdong University of Education, Guangzhou 510303, People's Republic of China.
  • Lin WQ; School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, People's Republic of China.
  • Jiang J; MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, People's Republic of China.
Inorg Chem ; 62(42): 17052-17056, 2023 Oct 23.
Article em En | MEDLINE | ID: mdl-37815023
ABSTRACT
Designing and innovating organic structure-directing agents is the key to synthesizing novel molecular sieve structures. Herein, we design a novel carbazolyl-modified template and further synthesize a two-dimensional layered aluminophosphate with [C17H21N2]3[Al3(PO4)4]·5H2O (denoted as ZHKU-2). ZHKU-2 is composed of AA-stacked [Al3P4O16]3- layers constructed from alternating AlO4 and PO3(=O) tetrahedrons to form a 4.6.8 network featured by capped six-ring secondary building units. Carbazolyl-templated ZHKU-2 exhibits strong purple fluorescence with a high quantum yield of 25.98%. This work expands aluminophosphate materials of the [Al3P4O16]3- family and provides a view for synthesizing new molecular sieves by exploring the organic luminescence structure-directing agents.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2023 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2023 Tipo de documento: Article