Synthesis of a chiral dinuclear Cu(II)-benzothiazolamine complex: evidence of cuprophilic interaction in its structure and exploration of its electrochemical properties and catalytic performance.
Dalton Trans
; 2023 Oct 30.
Article
em En
| MEDLINE
| ID: mdl-37902024
ABSTRACT
The synthesis of a chiral dinuclear [Cu(OAc)2(L1)]2 complex (A) and its analogues Cu(OAc)2(L1)2 (B), Cu(OAc)2(L1)PPh3 (C), CuBr(L1)PPh3 (D), and Cu(OAc)2(L2) (E) is described. The X-ray structure of A reveals a cuprophilic interaction (2.65 Å) and shows that L1 behaves as a monodentate ligand. The stereogenic centre in L1 aligns the NH group to form non-covalent interactions with the paddle-wheel acetate groups at variable distances (2.4-2.5 Å and 2.2-2.7 Å). Thermogravimetric analysis confirmed our hypothesis that two equivalents of L1 (B) or a combination of L1 and PPh3 (C) would disrupt the cuprophilic interaction. All complexes, except D, showed irreversible redox waves by cyclic voltammetry. Complexes C and E have lower oxidative peaks (at 10 V s-1) than complex A between +0.40 and +0.60 V. This highlights the influence of ligand(s) on the redox behaviour of Cu(II) complexes. The significance of this electrochemical behaviour was evident in the Chan-Lam (CL) coupling reaction, where 2.5 mol% of A successfully facilitated the formation of a C-N bond. This study showcased the structure, thermal stability, electrochemical properties and catalytic performance of a chiral dinuclear copper(II)-benzothiazolamine complex.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Dalton Trans
Ano de publicação:
2023
Tipo de documento:
Article